OwlTail

Organic Chemistry I/II - 2009-2010

Full chapter lectures and in-class recordings from Organic Chemistry I and II, at Anoka-Ramsey Community College in Coon Rapids, MN.Email andrew.aspaas@anokaramsey.edu from a .edu email address for access to the videos!

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Ch 24: Amines and heterocycles

Nomenclature; properties and basicity of amines; synthesis; reductive amination; Hoffman elimination; Sandmeyer reaction; heterocycles; spectroscopy

May 01 2010

1hr 15mins

Play

Ch 23: Carbonyl condensation reactions

Aldol reaction; dehydration; mixed aldol; intramolecular aldol; Claisen reaction (mixed, intramolecular); Michael reaction; Stork enamine reaction; Robinson annulation

Apr 29 2010

1hr 44mins

Play

Ch 22: Carbonyl alpha-substitution reactions

Keto-enol tautomerism; reactivity of enols; alpha-halogenation; enolate ion formation and reactivity; alkylation of enolate ions

Apr 22 2010

1hr 37mins

Play

Ch 21: Carboxylic acid derivatives

Naming; nucleophilic acyl substitution reactions; reactions of carboxylic acids; chemistry of acid halides, anhydrides, esters, amides; biological thioesters and acyl phosphates; step-growth polymers; spectroscopy

Apr 17 2010

2hr 2mins

Play

Ch 20a: Carboxylic acids

Carboxylic acid nomenclature; structure and properties; acidity; the Henderson-Hasselbalch equation; substituent effects on acidity; preparation; spectroscopy

Mar 22 2010

47mins

Play

Ch 19: Aldehydes and ketones: nucleophilic addition reactions

Aldehyde and ketone nomenclature; preparation of aldehydes and ketones; oxidation;hydration; cyanohydrin formation; Grignard and hydride reactions; imine and enamine formation; acetal formation; Wittig reaction; conjugate addition; spectroscopy

Mar 19 2010

2hr 4mins

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Ch 18: Ethers and epoxides; thiols and sulfides

Ether nomenclature, synthesis, cleavage; epoxide synthesis and ring-opening; thiols and sulfides; spectroscopy of ethers

Mar 18 2010

1hr 22mins

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Ch 17: Alcohols and phenols

Nomenclature; acid-base properties; synthesis of alcohols from alkenes; reduction of carbonyl compounds; Grignard reaction; conversion of alcohols into alkyl halides and tosylates; dehydration and oxidation of alcohols; protection; spectroscopy

Mar 08 2010

1hr 41mins

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Ch 16: Chemistry of benzene: electrophilic aromatic substitution

Bromination; other aromatic substitutions; alkylation of aromatic rings: the Friedel-Crafts reaction; substituent effects in aromatic rings; trisubstitued benzenes: additivity of effects; oxidation and reduction of aromatic compounds; synthesis

Feb 12 2010

1hr 51mins

Play

Ch 15: Benzene and aromaticity

Aromatic compound nomenclature; benzene MOs; 4n+2 rule; aromatic ions; aromatic heterocycles; polycyclic aromatic compounds; spectroscopy of aromatic compounds

Feb 04 2010

55mins

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Ch 14: Conjugated compounds and UV spectroscopy

Conjugation, MOs, allylic carbocations, Diels-Alder reaction, UV spectroscopy

Jan 24 2010

1hr 43mins

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Ch 12: Mass spectrometry and infrared spectroscopy

MS theory; interpretation of mass spectra; IR theory, interpretation of IR spectra

Jan 15 2010

1hr 21mins

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Jan 12: Intro to 2062

Jan 12 2010

33mins

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Ch 13: Nuclear magnetic resonance spectroscopy

NMR absorptions; chemical shift; 13C NMR; 1H NMR; integration; spin-spin splitting

Dec 12 2009

1hr 10mins

Play

Ch 11: Substitution and elimination

SN2 reaction; SN1 reaction; elimination reactions and Zaitsev's rule; E2 reaction and cyclohexane conformation; E1 reaction; summary of reactivity; synthesis practice

Nov 26 2009

1hr 55mins

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Nov 24: Exam 3 review; substitution and elimination

CA 13, CA 14

Nov 24 2009

21mins

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Ch 10: Organohalides

Nomenclature and structure of organohalides; radical halogenation; preparation of organohalides; Grignard and Gilman reagents

Nov 23 2009

1hr 34mins

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Ch 9: Stereochemistry

Chirality; enantiomers; assigning configuration; diastereomers; meso compounds; racemic mixtures; stereochemistry of reactions

Nov 19 2009

1hr 15mins

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Nov 17: Radical halogenation

CA 15, CA 13A

Nov 17 2009

20mins

Play

Ch 8: Alkynes: an intro to organic synthesis

Nomenclature; preparation of alkynes; addition of HX and X2; hydration and tautomerism; reduction; formation and alkylation of acetylide ions

Nov 09 2009

2hr 12mins

Play

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